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Vibrational spectroscopic study of the coordination of (2,2′-bipyridyl-4,4′-dicarboxylic acid)ruthenium(II) complexes to the surface of nanocrystalline titania
Journal article   Peer reviewed

Vibrational spectroscopic study of the coordination of (2,2′-bipyridyl-4,4′-dicarboxylic acid)ruthenium(II) complexes to the surface of nanocrystalline titania

K S Finnie, John R Bartlett and J L Woolfrey
Langmuir, Vol.14(10), pp.2741-2749
1998
url
https://doi.org/10.1021/la971060uView
Published Version

Abstract

The coordination of photosensitizing Ru(II) dyes to a nanocrystalline titania film, as employed in the Grätzel solar cell, has been examined by vibrational spectroscopy. The major infrared bands of the adsorbed dyes have been assigned by comparison with spectra (IR and Raman) of the parent dye molecules, and suggest a bidentate chelate or bridging coordination to the TiO 2 surface via two carboxylate groups per dye molecule.

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Chemistry, Multidisciplinary
Chemistry, Physical
Materials Science, Multidisciplinary

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#7 Affordable and Clean Energy

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