Versatile palladium(II) catalyzed Suzuki-Miyaura coupling in ethanol with a novel, stabilizing ligand

J J Ning; J F Wang; Z G Ren; David James Young; J P Lang

doi:10.1016/j.tet.2015.04.052

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Versatile palladium(II) catalyzed Suzuki-Miyaura coupling in ethanol with a novel, stabilizing ligand

Journal article

Peer reviewed

Versatile palladium(II) catalyzed Suzuki-Miyaura coupling in ethanol with a novel, stabilizing ligand

J J Ning, J F Wang, Z G Ren, David James Young and J P Lang

Tetrahedron, Vol.71(23), pp.4000-4006

2015

DOI: https://doi.org/10.1016/j.tet.2015.04.052

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Abstract

Organic Chemistry

Medicinal and Biomolecular Chemistry

SuzukieMiyaura coupling

Palladium(II)

P-Donor ligand

Aryl halide

Arylboronic acid

Suzuki-Miyaura coupling reactions of arylboronic acids with aryl bromides were mediated by PdCl2 and bdppmapy (N,N-bis-(diphenylphosphanylmethyl)-2-aminopyridine) that both stabilizes and solubilizes the catalyst in predominantly ethanol as a solvent. Excellent yields for a wide variety of substrates were obtained under relatively mild conditions in this 'green' solvent.

Details

Title: Versatile palladium(II) catalyzed Suzuki-Miyaura coupling in ethanol with a novel, stabilizing ligand
Authors: J J Ning (Author) - Soochow University, China
J F Wang (Author) - Soochow University, China
Z G Ren (Author) - Soochow University, China
David James Young (Author) - Monash University Malaysia, Malaysia
J P Lang (Author) - Soochow University, China
Publication details: Tetrahedron, Vol.71(23), pp.4000-4006
Publisher: Pergamon
Date published: 2015
DOI: 10.1016/j.tet.2015.04.052
ISSN: 0040-4020
Organisation Unit: University of the Sunshine Coast, Queensland
Language: English
Record Identifier: 99449495702621
Output Type: Journal article

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Collaboration types: Domestic collaboration; International collaboration
Web Of Science research areas: Chemistry, Organic