Journal article
Unexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii)
Chemical Communications, Vol.44, pp.6831-6833
2009
Abstract
The reaction of [PtII(2-phenylpyridine)(acac)] and benzothiazolium bromide yields the N,S-heterocyclic carbene ligand trans to pyridyl while, surprisingly, a very similar N,N-heterocyclic carbene coordinates predominantly trans to the cyclometallated carbon. © 2009 The Royal Society of Chemistry.
Details
- Title
- Unexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii)
- Authors
- S K Yen (Author) - National University of Singapore, SingaporeDavid James Young (Author) - Griffith UniversityH V Huynh (Author) - National University of Singapore, SingaporeL L Koh (Author) - National University of Singapore, SingaporeT S A Hor (Author) - National University of Singapore, Singapore
- Publication details
- Chemical Communications, Vol.44, pp.6831-6833
- Publisher
- Royal Society of Chemistry (R S C) Publications
- Date published
- 2009
- DOI
- 10.1039/b914036k
- ISSN
- 1359-7345
- Organisation Unit
- University of the Sunshine Coast, Queensland
- Language
- English
- Record Identifier
- 99449357702621
- Output Type
- Journal article
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