Thermal decomposition of allylic sulfinic acids: Confirmation of a retro-ene mechanism

M D King; R E Sue; Rodney H White; David James Young

doi:10.1039/C39930001797

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Thermal decomposition of allylic sulfinic acids: Confirmation of a retro-ene mechanism

Journal article

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Thermal decomposition of allylic sulfinic acids: Confirmation of a retro-ene mechanism

M D King, R E Sue, Rodney H White and David James Young

Journal of the Chemical Society, Chemical Communications, (24), pp.1797-1798

1993

DOI: https://doi.org/10.1039/C39930001797

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Abstract

allylic sulfinic acids

The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.

Details

Title: Thermal decomposition of allylic sulfinic acids: Confirmation of a retro-ene mechanism
Authors: M D King (Author)
R E Sue (Author)
Rodney H White (Author)
David James Young (Author)
Publication details: Journal of the Chemical Society, Chemical Communications, (24), pp.1797-1798
Publisher: Royal Society of Chemistry (R S C) Publications
DOI: 10.1039/C39930001797
ISSN: 0022-4936
Organisation Unit: University of the Sunshine Coast, Queensland
Language: English
Record Identifier: 99449935802621
Output Type: Journal article

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