The thermal desulfination of allylic sulfonyl halides

M D King; R E Sue; Rodney H White; David James Young

doi:10.1016/S0040-4039(97)00911-8

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The thermal desulfination of allylic sulfonyl halides

Journal article

Peer reviewed

The thermal desulfination of allylic sulfonyl halides

M D King, R E Sue, Rodney H White and David James Young

Tetrahedron Letters, Vol.38(25), pp.4493-4496

1997

DOI: https://doi.org/10.1016/S0040-4039(97)00911-8

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Abstract

allyl compound

halide

sulfinic acid derivative

Allylic sulfonyl halides can be generated by halogenolysis of the corresponding triorganotin sulfinates. Allylic sulfonyl bromides and iodides undergo a first order, thermal desulfination with allylic rearrangement to yield the corresponding allylic halides. The desulfination of a cyclic allylic sulfonyl bromide is stereospecific, proceeding with γ-syn bromine migration.

Details

Title: The thermal desulfination of allylic sulfonyl halides
Authors: M D King (Author) - Griffith University
R E Sue (Author) - Griffith University
Rodney H White (Author) - Griffith University
David James Young (Author) - Griffith University
Publication details: Tetrahedron Letters, Vol.38(25), pp.4493-4496
Publisher: Pergamon
Date published: 1997
DOI: 10.1016/S0040-4039(97)00911-8
ISSN: 0040-4039
Organisation Unit: University of the Sunshine Coast, Queensland
Language: English
Record Identifier: 99449196602621
Output Type: Journal article

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