Journal article
The thermal decomposition of allylic sulfinic acids: A study of a retro-ene transition state
Journal of the Chemical Society, Chemical Communications, (11), pp.1381-1382
1994
Abstract
The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.
Details
- Title
- The thermal decomposition of allylic sulfinic acids: A study of a retro-ene transition state
- Authors
- S D Hiscock (Author)N S Isaacs (Author)M D King (Author)David James Young (Author)
- Publication details
- Journal of the Chemical Society, Chemical Communications, (11), pp.1381-1382
- Publisher
- Royal Society of Chemistry (R S C) Publications
- Date published
- 1994
- DOI
- 10.1039/C39940001381
- ISSN
- 0022-4936
- Organisation Unit
- University of the Sunshine Coast, Queensland
- Language
- English
- Record Identifier
- 99450082202621
- Output Type
- Journal article
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