The solvent promoted addition of tetraallyltin to aldehydes: A convenient and chemoselective allylation procedure

T M Cokley; R L Marshall; A McCluskey; David James Young

doi:10.1016/0040-4039(96)00149-9

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The solvent promoted addition of tetraallyltin to aldehydes: A convenient and chemoselective allylation procedure

Journal article

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The solvent promoted addition of tetraallyltin to aldehydes: A convenient and chemoselective allylation procedure

T M Cokley, R L Marshall, A McCluskey and David James Young

Tetrahedron Letters, Vol.37(11), pp.1905-1908

1996

DOI: https://doi.org/10.1016/0040-4039(96)00149-9

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Abstract

allyl compound

Aldehydes 2a-e react with tetraallyltin (1, 0.25 equiv.) in methanol or orther polar solvent at room temperature (ca 30°C, < 20 h) to provide the corresponding homoallyl alcohols 3a-e in 69-98% yield. No additional catalysis is required.

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Title: The solvent promoted addition of tetraallyltin to aldehydes: A convenient and chemoselective allylation procedure
Authors: T M Cokley (Author) - Griffith University
R L Marshall (Author) - Griffith University
A McCluskey (Author) - Griffith University
David James Young (Author) - Griffith University
Publication details: Tetrahedron Letters, Vol.37(11), pp.1905-1908
Publisher: Pergamon
Date published: 1996
DOI: 10.1016/0040-4039(96)00149-9
ISSN: 0040-4039
Organisation Unit: University of the Sunshine Coast, Queensland
Language: English
Record Identifier: 99449394302621
Output Type: Journal article

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