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The high pressure addition of aldehydes to allylstannanes: A 'Diels-Alder like' transition state
Journal article   Peer reviewed

The high pressure addition of aldehydes to allylstannanes: A 'Diels-Alder like' transition state

N S Isaacs, L Maksimovic, G B Rintoul and David James Young
Journal of the Chemical Society, Chemical Communications, (23), pp.1749-1750
1992
url
https://doi.org/10.1039/C39920001749View
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Abstract

allylstannanes
The activation volume for the addition of chloral to allyltributylstannane was found to be -33.4±0.6 cm3 mol-1, which is consistent with a concerted, cyclic transition state.

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