Journal article
The electrophilic cleavage of cyclopropylcarbinylstannanes. Confirmation of traylor's prediction
Tetrahedron Letters, Vol.32(6), pp.807-810
1991
Abstract
The reaction of cyclopropylcarbinyltrialkylstannanes (CPCSnR3) 1a (R=Me) and 1b (R=Bu) with sulfur dioxide in chloroform or methanol yields the homoallylic tin sulphinates 2a and 2b respectively. The reaction of 1a with iodine in chloroform yields predominantly 4-iodo-1-butene (3) and trimethyltin iodide while in methanol the corresponding reaction yields CPCSnMe2I (4) and methyl iodide. © 1991.
Details
- Title
- The electrophilic cleavage of cyclopropylcarbinylstannanes. Confirmation of traylor's prediction
- Authors
- Andrew J Lucke (Author) - Griffith UniversityDavid James Young (Author) - Griffith University
- Publication details
- Tetrahedron Letters, Vol.32(6), pp.807-810
- Publisher
- Pergamon
- Date published
- 1991
- DOI
- 10.1016/S0040-4039(00)74893-3
- ISSN
- 0040-4039
- Organisation Unit
- University of the Sunshine Coast, Queensland
- Language
- English
- Record Identifier
- 99449192702621
- Output Type
- Journal article
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- Chemistry, Organic
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