Journal article
Switchable Synthesis of Z‐Homoallylic Boronates and E‐Allylic Boronates by Enantioselective Copper‐Catalyzed 1,6‐Boration
Chemistry: A European Journal, Vol.24(33), pp.8315-8319
2018
PMID: 29665113
Abstract
The enantioselective Cu‐catalyzed 1,6‐boration of (E,E)‐α,β,γ,δ‐unsaturated ketones is described, which gives homoallylic boronates with high enantiomeric purity and unexpectedly high Z‐selectivity. By changing the solvent, the outcome can be altered to give E‐allylic boronates.
Flip the switch: The enantioselective Cu‐catalyzed 1,6‐boration of (E,E)‐α,β,γ,δ‐unsaturated ketones is described, which gives homoallylic boronates with high enantiomeric purity and unexpectedly high Z‐selectivity. By changing the solvent, the outcome can be altered to give E‐allylic boronates.
Details
- Title
- Switchable Synthesis of Z‐Homoallylic Boronates and E‐Allylic Boronates by Enantioselective Copper‐Catalyzed 1,6‐Boration
- Authors
- Yunfei Luo (Corresponding Author) - University of EdinburghSteven M. Wales (Author) - University of NottinghamStamatis E. Korkis (Author) - University of NottinghamIain D. Roy (Author) - University of EdinburghWilliam Lewis (Author) - University of NottinghamHon Wai Lam (Author) - University of Edinburgh
- Publication details
- Chemistry: A European Journal, Vol.24(33), pp.8315-8319
- Publisher
- Wiley-VCH Verlag GmbH & Co. KGaA
- DOI
- 10.1002/chem.201801804
- ISSN
- 1521-3765
- PMID
- 29665113
- Organisation Unit
- Student Services and Engagement; School of Science, Technology and Engineering
- Language
- English
- Record Identifier
- 99707364502621
- Output Type
- Journal article
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- Domestic collaboration
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- Web Of Science research areas
- Chemistry, Multidisciplinary
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