Suzuki-Miyaura cross-coupling reaction of aryl chlorides with aryl boronic acids catalyzed by a palladium dichloride adduct of N-diphenylphosphanyl-2-aminopyridine

Lin-Yan Xu; Chun-Yu Liu; Shi-Yuan Liu; Zhi-Gang Ren; David James Young; Jian-Ping Lang

doi:10.1016/j.tet.2017.04.034

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Suzuki-Miyaura cross-coupling reaction of aryl chlorides with aryl boronic acids catalyzed by a palladium dichloride adduct of N-diphenylphosphanyl-2-aminopyridine

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Suzuki-Miyaura cross-coupling reaction of aryl chlorides with aryl boronic acids catalyzed by a palladium dichloride adduct of N-diphenylphosphanyl-2-aminopyridine

Lin-Yan Xu, Chun-Yu Liu, Shi-Yuan Liu, Zhi-Gang Ren, David James Young and Jian-Ping Lang

Tetrahedron, Vol.73(22), pp.3125-3132

2017

DOI: https://doi.org/10.1016/j.tet.2017.04.034

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Abstract

aryl chloride

aryl boronic acid

Suzuki-Miyaura coupling

P-N donor ligand

palladium(II)

One palladium dichloride adduct of a phosphine-pyridine ligand N-diphenylphosphanyl-2-aminopyridine (L1) [(L1)PdCl2] (1) has been prepared and structurally characterized. Compound 1 can be used as an effective catalyst for the Suzuki-Miyaura cross-coupling reactions of unreactive aryl chlorides with aryl boronic acids, and worked much better than its mono- or bidentate phosphine ligands. The reactions with a wide scope of substrates proceeded to give desired products in good to excellent yields.

Details

Title: Suzuki-Miyaura cross-coupling reaction of aryl chlorides with aryl boronic acids catalyzed by a palladium dichloride adduct of N-diphenylphosphanyl-2-aminopyridine
Authors: Lin-Yan Xu (Author) - Soochow University, China
Chun-Yu Liu (Author) - Soochow University, China
Shi-Yuan Liu (Author) - Soochow University, China
Zhi-Gang Ren (Author) - Soochow University, China
David James Young (Author) - University of the Sunshine Coast - Faculty of Science, Health, Education and Engineering
Jian-Ping Lang (Author) - Soochow University, China
Publication details: Tetrahedron, Vol.73(22), pp.3125-3132
Publisher: Pergamon
Date published: 2017
DOI: 10.1016/j.tet.2017.04.034
ISSN: 0040-4020; 0040-4020
Organisation Unit: University of the Sunshine Coast, Queensland
Language: English
Record Identifier: 99450443002621
Output Type: Journal article
Research Statement: false

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Collaboration types: Domestic collaboration; International collaboration
Web Of Science research areas: Chemistry, Organic