Structure and photoluminescence of cubane-like [Cu4I4] cluster-based 1D coordination polymer assembled with bis(triazole)pyridine ligand

Shi-Qiang Bai; Karen Lin Le; David James Young; T S Andy Hor

doi:10.1016/j.jorganchem.2017.03.040

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Structure and photoluminescence of cubane-like [Cu4I4] cluster-based 1D coordination polymer assembled with bis(triazole)pyridine ligand

Journal article

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Structure and photoluminescence of cubane-like [Cu4I4] cluster-based 1D coordination polymer assembled with bis(triazole)pyridine ligand

Shi-Qiang Bai, Karen Lin Le, David James Young and T S Andy Hor

Journal of Organometallic Chemistry, Vol.849-850, pp.137-141

2017

DOI: https://doi.org/10.1016/j.jorganchem.2017.03.040

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Abstract

bis(triazole) ligand

cubane-like [Cu4I4] cluster

coordination polymer

luminescence

[L2Cu4I4]n (1) based on a cubic [Cu4I4] node and ditopic, bridging bis(triazole) (L = 2,6-bis((1H-1,2,3- triazol-1-yl)methyl)pyridine) is a unique and highly symmetric cubane cluster based coordination polymer with strong yellow emission. Comparison with similar coordination polymers permits a structure activity relationship and reveals that the emission energy for these [Cu4I4] cluster-based materials occurs in the mid-range of Cuâ‹…â‹…â‹…Cu distances and tetrahedral geometry index values.

Details

Title: Structure and photoluminescence of cubane-like [Cu4I4] cluster-based 1D coordination polymer assembled with bis(triazole)pyridine ligand
Authors: Shi-Qiang Bai (Author) - Institute of Materials Research and Engineering, Republic of Singapore
Karen Lin Le (Author) - Institute of Materials Research and Engineering, Republic of Singapore
David James Young (Author) - University of the Sunshine Coast - Faculty of Science, Health, Education and Engineering
T S Andy Hor (Author) - Institute of Materials Research and Engineering, Republic of Singapore
Publication details: Journal of Organometallic Chemistry, Vol.849-850, pp.137-141
Publisher: Elsevier BV
Date published: 2017
DOI: 10.1016/j.jorganchem.2017.03.040
ISSN: 0022-328X
Organisation Unit: University of the Sunshine Coast, Queensland
Language: English
Record Identifier: 99450519902621
Output Type: Journal article

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Collaboration types: Domestic collaboration; International collaboration
Web Of Science research areas: Chemistry, Inorganic & Nuclear; Chemistry, Organic