Silicon Lewis acids promote the addition of aldehydes to allylstannanes without transmetallation

R Marshall; David James Young

doi:10.1016/S0040-4039(00)91624-1

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Silicon Lewis acids promote the addition of aldehydes to allylstannanes without transmetallation

Journal article

Peer reviewed

Silicon Lewis acids promote the addition of aldehydes to allylstannanes without transmetallation

R Marshall and David James Young

Tetrahedron Letters, Vol.33(10), pp.1365-1368

1992

DOI: https://doi.org/10.1016/S0040-4039(00)91624-1

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Abstract

Organic Chemistry

Medicinal and Biomolecular Chemistry

ether derivative

organosilicon derivative

The Lewis acids CH3SiCl3 (0.33 - 1.0 equivalents) and (CH3O)2SiCH3Cl (1.0 equivalent) promote the addition of aldehydes to allylstannanes to yield the homoallyl silyl ethers 1a, 1b, 3 - 5. These reactions do not proceed via an initial transmetallation. © 1992.

Details

Title: Silicon Lewis acids promote the addition of aldehydes to allylstannanes without transmetallation
Authors: R Marshall (Author) - Griffith University
David James Young (Author) - Griffith University
Publication details: Tetrahedron Letters, Vol.33(10), pp.1365-1368
Publisher: Pergamon
Date published: 1992
DOI: 10.1016/S0040-4039(00)91624-1
ISSN: 0040-4039
Organisation Unit: University of the Sunshine Coast, Queensland
Language: English
Record Identifier: 99449608002621
Output Type: Journal article

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