Journal article
Rectangle and [2]catenane from cluster modular construction
Chemical Communications, Vol.54(33), pp.4168-4171
2018
Abstract
Reaction of [Et4N][Tp*WS3] (1) with [Cu(MeCN)4]PF6, CsCl, isonicotinic acid and CuCN, and treatment of [Et4N][Tp*WS3(CuCl)3] (2)/[Et4N][{Tp*WS3Cu3Cl}2([small mu ]-Cl)2([small mu ]4-Cl)] (3) with AgOTf and bpp (Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate; bpp = 1,3-di(4-pyridyl)propane) give rise to [Et4N]2[{Tp*WS3Cu3(CN)0.5}2([small mu ]-Cl)2([small mu ]4-Cl)]2(PF6)2 (4) and [(Tp*WS3Cu3)2([small mu ]3-Cl)2(bpp)3]2(OTf)4 (5), respectively. Compounds 4 and 5 feature cluster-based rectangle and [2]catenane architecture, and both exhibit enhanced third-order nonlinear optical responses relative to those of 1.
Details
- Title
- Rectangle and [2]catenane from cluster modular construction
- Authors
- X T Qiu (Author) - Soochow University, People's Republic of ChinaRui Yao (Author) - Soochow University, People's Republic of ChinaWen-Fa Zhou (Author) - Soochow University, People's Republic of ChinaMeng-Di Liu (Author) - Soochow University, People's Republic of ChinaQuan Liu (Author) - Soochow University, People's Republic of ChinaYing-Lin Song (Author) - Soochow University, People's Republic of ChinaDavid James Young (Author) - University of the Sunshine Coast - Faculty of Science, Health, Education and EngineeringWen-Hua Zhang (Author) - Soochow University, People's Republic of ChinaJian-Ping Lang (Author) - Soochow University, People's Republic of China
- Publication details
- Chemical Communications, Vol.54(33), pp.4168-4171
- Publisher
- Royal Society of Chemistry (R S C) Publications
- Date published
- 2018
- DOI
- 10.1039/C8CC01950A
- ISSN
- 1359-7345
- Organisation Unit
- University of the Sunshine Coast, Queensland
- Language
- English
- Record Identifier
- 99451101902621
- Output Type
- Journal article
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