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Polymeric anhydrous sodium 2-amino-benzensulfonate
Journal article   Open access   Peer reviewed

Polymeric anhydrous sodium 2-amino-benzensulfonate

G Smith, U D Wermuth, David James Young and P C Healy
Acta Crystallographica Section E: Structure Reports Online, Vol.60(Part 6), pp.m836-m838
2004
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https://doi.org/10.1107/S1600536804011456View
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Abstract

amines crystal structure hydrogen molecular structure nitrogen sulfur compounds
The crystal structure of anhydrous sodium 2-aminobenzene-sulfonate, [Na(C6H6NO3S)]n, reveals the presence of a two-dimensional sandwich polymer structure based on a distorted octahedral six-coordinate NaO5N repeating unit. O-Donor atoms are from five different sulfonate groups [Na-O = 2.294 (3)-2.532 (3) Ã…] and an amine nitrogen [Na-N = 2.572 (3) Ã…], completing a six-membered chelate ring including Na. Hydrogen bonds also stabilize the core structure. The outer layers of the sandwich comprise the unassociated benzene rings. © 2004 International Union of Crystallography Printed in Great Britain - all rights reserved.

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