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Nitrogen-rich azoles as ligand spacers in coordination polymers
Journal article   Peer reviewed

Nitrogen-rich azoles as ligand spacers in coordination polymers

S Q Bai, David James Young and T S A Hor
Chemistry - An Asian Journal, Vol.6(2), pp.292-304
2011
url
https://doi.org/10.1002/asia.201000698View
Published Version

Abstract

azoles coordination polymers nitrogen heterocycles oligomers supramolecules
N-heterocycle-based ligands are versatile building-blocks for coordination oligomer and polymer assemblies of first-row transition metals. Herein, we review recent developments in the design and synthesis of some nitrogen-rich azole-based ligands, their assembly modes in coordination oligomers and polymers, and the potential applications of the resulting metallosupramolecules. Spacer Oddity: Hybrid azoles support a myriad of coordination polymers by serving as flexible and adaptable spacers through a range of coordination modes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Chemistry, Multidisciplinary
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