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Morphology dependent electron transport in an n-type electron accepting small molecule for solar cell applications
Journal article   Peer reviewed

Morphology dependent electron transport in an n-type electron accepting small molecule for solar cell applications

Karsten B Krueger, Paul E Schwenn, Ke Gui, Almantas Pivrikas, Paul Meredith and Paul L Burn
Applied Physics Letters, Vol.98(8)
2011
url
https://doi.org/10.1063/1.3556280View
Published Version

Abstract

We report on the charge transport properties of a simple solution processable small-molecule electron acceptor, 2-[{7-(9,9-di- n -propyl- 9H -fluoren-2-yl)benzo [c] [1,2,5]thiadiazol-4-yl}methylene]malononitrile (K12), designed for use in bulk-heterojunction organic photovoltaic cells. It was found that the molecular order in as-cast films can be dramatically improved by annealing at moderate temperatures (60 °C), which leads to a greatly enhanced electron mobility. Using the photoinduced charge extraction in linearly increasing voltage technique we measured bulk electron mobilities to be as high as 10-4 cm2 V-1 s-1, comparable with some of the best nonfullerene acceptor materials reported to date.

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