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Metal oxide semiconducting interfacial layers for photovoltaic and photocatalytic applications
Journal article   Open access   Peer reviewed

Metal oxide semiconducting interfacial layers for photovoltaic and photocatalytic applications

Naveen Elumalai, Chellappan Vijila, Rajan Jose, Ashraf Uddin and Seeram Ramakrishna
Materials for renewable and sustainable energy, Vol.4(3), pp.1-25
2015
pdf
s40243-015-0054-95.22 MBDownloadView
Published Version Open Access CC BY V4.0
url
https://doi.org/10.1007/s40243-015-0054-9View
Published Version Open CC BY V4.0

Abstract

photovoltaic metal oxide semiconductor interfacial layers renewable energy photocatalysts
The present review rationalizes the significance of the metal oxide semiconductor (MOS) interfaces in the field of photovoltaics and photocatalysis. This perspective considers the role of interface science in energy harvesting using organic photovoltaics (OPVs) and dye-sensitized solar cells (DSSCs). These interfaces include large surface area junctions between photoelectrodes and dyes, the interlayer grain boundaries within the photoanodes, and the interfaces between photoactive layers and the top and bottom contacts. Controlling the collection and minimizing the trapping of charge carriers at these boundaries is crucial to overall power conversion efficiency of solar cells. Similarly, MOS photocatalysts exhibit strong variations in their photocatalytic activities as a function of band structure and surface states. Here, the MOS interface plays a vital role in the generation of OH radicals, which forms the basis of the photocatalytic processes. The physical chemistry and materials science of these MOS interfaces and their influence on device performance are also discussed.

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Materials Science, Multidisciplinary
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