Journal article
Metal-Organic Frameworks via Emissive Metal-Carboxylate Zwitterion Intermediates
ChemPlusChem, Vol.80(8), pp.1231-1234
2015
Abstract
Pyridinemethanol-carboxylate esters form octahedral complexes with Zn(NO3)2 in aqueous DMF that subsequently undergo hydrolysis at elevated temperatures to form metal-carboxylate zwitterions. In situ deprotonation of the hydroxy group leads to thermally robust, neutral MOFs. This stepwise synthesis can be controlled by temperature and is made possible by the subtle difference in reactivity of the functional groups.
Details
- Title
- Metal-Organic Frameworks via Emissive Metal-Carboxylate Zwitterion Intermediates
- Authors
- M Armaghan (Author) - National University of Singapore, SingaporeX J Shang (Author) - Chemical Engineering and Materials Sciences Sanchow University, ChinaY Q Yuan (Author) - Chemical Engineering and Materials Sciences Sanchow University, ChinaDavid James Young (Author) - Monash University Malaysia, MalaysiaW H Zhang (Author) - Chemical Engineering and Materials Sciences Sanchow University, ChinaT S A Hor (Author) - National University of Singapore, SingaporeJ P Lang (Author) - Chemical Engineering and Materials Sciences Sanchow University, China
- Publication details
- ChemPlusChem, Vol.80(8), pp.1231-1234
- Publisher
- Wiley - V C H Verlag GmbH & Co. KGaA
- Date published
- 2015
- DOI
- 10.1002/cplu.201500134
- ISSN
- 2192-6506
- Organisation Unit
- University of the Sunshine Coast, Queensland
- Language
- English
- Record Identifier
- 99449603402621
- Output Type
- Journal article
Metrics
4 File views/ downloads
483 Record Views
InCites Highlights
These are selected metrics from InCites Benchmarking & Analytics tool, related to this output
- Collaboration types
- Domestic collaboration
- International collaboration
- Web Of Science research areas
- Chemistry, Multidisciplinary