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High-pressure synthesis of novel thietane monomers and polymers
Journal article   Peer reviewed

High-pressure synthesis of novel thietane monomers and polymers

N M Puspawati and David James Young
High Pressure Research, Vol.28(4), pp.675-679
2008
url
https://doi.org/10.1080/08957950802526451View
Published Version

Abstract

high pressure polymerization synthesis
High-pressure polymerization of thietane with a neutral nucleophile provides a quantitative yield of high molecular weight polythietane suggesting a large, negative activation volume from electrostriction of solvent in the transition state. The corresponding reaction of 3-aryloxythietanes can be achieved but requires much harsher conditions.

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Physics, Multidisciplinary

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