Journal article
Functionalized 1,2,3-triazoles as building blocks for photoluminescent POLOs (polymers of oligomers) of copper(i)
Dalton transactions (Cambridge, England : 2003), Vol.39(10), pp.2631-2636
2010
Abstract
Two 3-D and one 2-D metal-organic frameworks [Cu8I 8(L1)4]n (1), [Cu8I 8(L2)4]n (2) and [Cu4I 4(L3)2]n (3) were synthesized using three novel pyridine and pyrazole supported 1,2,3-triazoles, 1-(4-picolyl)-4-butyl-1H-1,2, 3-triazole (L1), 1-(4-picolyl)-4-pentyl-1H-1,2,3-triazole (L2) and 1-(4-picolyl)-4-(3,5-dimethylpyrazolylmethyl)-1H-1,2,3-triazole (L3). In both complexes 1 and 2, there co-exist a 1-D Cu(i) oligomer and Cu4 tetrahedron cluster in the 3-D polymeric structures. Complex 3 shows a 2-D (4, 4) net with the stair-step Cu4I4 as node and L3 as a building block. All three complexes exhibit photoluminescence. © The Royal Society of Chemistry 2010.
Details
- Title
- Functionalized 1,2,3-triazoles as building blocks for photoluminescent POLOs (polymers of oligomers) of copper(i)
- Authors
- S Q Bai (Author) - National University of Singapore, SingaporeJ Y Kwang (Author) - National University of Singapore, SingaporeL L Koh (Author) - National University of Singapore, SingaporeDavid James Young (Author) - Griffith UniversityT S A Hor (Author) - National University of Singapore, Singapore
- Publication details
- Dalton transactions (Cambridge, England : 2003), Vol.39(10), pp.2631-2636
- Publisher
- Royal Society of Chemistry (R S C) Publications
- Date published
- 2010
- DOI
- 10.1039/b918223c
- ISSN
- 1477-9226
- Organisation Unit
- University of the Sunshine Coast, Queensland
- Language
- English
- Record Identifier
- 99449474502621
- Output Type
- Journal article
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- Domestic collaboration
- International collaboration
- Web Of Science research areas
- Chemistry, Inorganic & Nuclear