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Evaluation of excess molar volumes of n-butanol with nitrobenzene-aniline-acetonitrile binary liquid mixtures at temperatures of 298.15, 303.15, 308.15, and 313.15 K
Journal article   Peer reviewed

Evaluation of excess molar volumes of n-butanol with nitrobenzene-aniline-acetonitrile binary liquid mixtures at temperatures of 298.15, 303.15, 308.15, and 313.15 K

Mohammad A Wahab, M A Islam, M A Ali and M A Mottaleb
Physics and Chemistry of Liquids, Vol.41(2), pp.189-195
2003
url
https://doi.org/10.1080/00319100307953View
Published Version

Abstract

excess molar volumes binary liquid mixtures n-butanol nitrobenzene aniline acetonitrile
The excess molar volumes (VE m) of binary liquid mixture defined here: n-butanol and nitrobenzene, n-butanol and aniline, and n-butanol and acetonitrile have been determined as a function of mole fraction of n-butanol at temperatures of 298.15, 303.15, 308.15, and 313.15 K by a calibrated bi-capillary pycnometer. The VE m were obtained as negative values over the entire composition range in the order of n-butanol + nitrobenzene, < n-butanol + aniline, and <n-butanol + acetonitrile systems. The negative magnitude of VE m suggests the presence of specific intermolecular interaction in the three liquid mixtures.

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Domestic collaboration
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Web Of Science research areas
Chemistry, Physical
Physics, Condensed Matter
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