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Europium-exchanged synthetic faujasite zeolites: A luminescence spectroscopic study
Journal article   Peer reviewed

Europium-exchanged synthetic faujasite zeolites: A luminescence spectroscopic study

John R Bartlett, R P Cooney and R A Kydd
Journal of Catalysis, Vol.114(1), pp.58-70
1988
url
https://doi.org/10.1016/0021-9517(88)90009-7View
Published Version

Abstract

Physical Chemistry (incl. Structural) Chemical Engineering
A series of thermally activated europium-exchanged X and Y zeolites have been characterized by luminescence spectroscopy. The distribution of Eu(III) species has been deduced for both EuX and EuY samples (held at 20 K), on the basis of the observed 5D0 → 7F0 luminescence emissions. For thermally activated EuY, only site SI′ was found to be occupied by Eu(III) cations. In contrast, Eu(III) species were found to be distributed between sites SI′ and SII in thermally activated samples of EuX. The effects of Eu(III) hydrolysis on the observed luminescence spectra are also discussed.

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