Eliminative fission of hydroxythietanes: transition structures for cleavage of 4-membered rings

David James Young; Charles J M Stirling

doi:10.1039/C39870000552

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Eliminative fission of hydroxythietanes: transition structures for cleavage of 4-membered rings

Journal article

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Eliminative fission of hydroxythietanes: transition structures for cleavage of 4-membered rings

David James Young and Charles J M Stirling

Journal of the Chemical Society, Chemical Communications, (8), pp.552-553

1987

DOI: https://doi.org/10.1039/C39870000552

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Abstract

Chemical Sciences

fission

Pathways in nucleophilic fission of hydroxythietanes are determined by the oxidation state of sulphur; for eliminative fission, activation parameters, substituent effects, and comparison with unstrained analogues all suggest a greater degree of ring cleavage in the transition structure for thietanes than for cyclobutanes.

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Title: Eliminative fission of hydroxythietanes: transition structures for cleavage of 4-membered rings
Authors: David James Young (Author)
Charles J M Stirling (Author)
Publication details: Journal of the Chemical Society, Chemical Communications, (8), pp.552-553
Publisher: Royal Society of Chemistry (R S C) Publications
Date published: 1987
DOI: 10.1039/C39870000552
ISSN: 0022-4936
Organisation Unit: University of the Sunshine Coast, Queensland
Language: English
Record Identifier: 99449235002621
Output Type: Journal article

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