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Electrophilic substitution with allylic rearrangement (SE′). Syn stereoselectivity in sulfur dioxide insertion into some cyclohex-2-enylstannanes
Journal article   Peer reviewed

Electrophilic substitution with allylic rearrangement (SE′). Syn stereoselectivity in sulfur dioxide insertion into some cyclohex-2-enylstannanes

David James Young and W Kitching
Journal of Organic Chemistry, Vol.48(4), pp.614-615
1983
url
https://doi.org/10.1021/jo00152a045View
Published Version

Abstract

electrophilic substitution
Sulfur dioxide insertion into cis- and trans-(5-alkylcyclohex-2-enyl)trimethylstannanes is demonstrated to be γ regio- and syn stereospecific, in contrast to the γ regiospecific but anti stereoselective trifluoro-acetolyses of these stannanes. © 1983 American Chemical Society.

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