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Electrophilic substitution with allylic rearrangement (SE′). syn or anti stereoselectivity in trifluoroacetolysis of 4-alkylcyclohex-2-enylsilanes, -germanes and -stannanes
Journal article   Peer reviewed

Electrophilic substitution with allylic rearrangement (SE′). syn or anti stereoselectivity in trifluoroacetolysis of 4-alkylcyclohex-2-enylsilanes, -germanes and -stannanes

David James Young, W Kitching and G Wickham
Tetrahedron Letters, Vol.24(51), pp.5789-5792
1983
url
https://doi.org/10.1016/S0040-4039(00)94202-3View
Published Version

Abstract

electrophilic substitution
Cis-4-alkylcyclohex-2-enyl derivatives of silicon, germanium and tin, with quasiaxial metallo groups, experience stereospecific γ-anti trifluoroacetolysis (to yield 4-alkylcyclohexene), whereas the corresponding trans-isomers show less specificity. © 1983.

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