Logo image
Electrogenerated chemiluminescence triggered by electroseparation of Ru(bpy)32+ across a supported liquid membrane
Journal article   Peer reviewed

Electrogenerated chemiluminescence triggered by electroseparation of Ru(bpy)32+ across a supported liquid membrane

G A Crespo, G Mistlberger and Eric Bakker
Chemical Communications, Vol.47(42), pp.11644-11646
2011
url
https://doi.org/10.1039/C1CC14822BView
Published Version

Abstract

ion-selective membranes electrogenerated chemiluminescence (ECL)
We demonstrate here for the first time the detection of electrogenerated chemiluminescence (ECL) upon selective, electrochemically triggered tris(2,2′-bipyridyl)ruthenium(II) (Ru(bpy)32+) transport across a supported liquid membrane doped with a lipophilic cation-exchanger. This approach allows one to separate the location of ECL generation from the sample compartment, thereby avoiding the contamination of the sample with compounds necessary for ECL.

Details

Metrics

5 File views/ downloads
323 Record Views
Logo image