Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN 2)quinoline- κN]zinc

M H B Najib; A L Tan; David James Young; S W Ng; E R T Tiekink

doi:10.1107/S1600536812014390

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Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN 2)quinoline- κN]zinc

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Peer reviewed

Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN 2)quinoline- κN]zinc

M H B Najib, A L Tan, David James Young, S W Ng and E R T Tiekink

Acta Crystallographica Section E: Structure Reports Online, Vol.68(Part 5), pp.m571-m572

2012

DOI: https://doi.org/10.1107/S1600536812014390

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Abstract

tetra

The ZnII atom in the title compound, [ZnCl2(C 14H13N3)], is coordinated by a Cl 2N2 donor set defined by quinoline and pyrazole N atoms of the chelating ligand and two Cl atoms. Distortions from the ideal tetra-hedral geometry relate to the restricted bite angle of the chelating ligand [N - Zn - N = 78.54 (12)°]. In the crystal, molecules are connected into a three-dimensional structure by C - H⋯Cl inter-actions, involving both Cl atoms, and π-π inter-actions that occur between the pyrazole ring and each of the pyridine and benzene rings of the quinoline residue [inter-centroid distances = 3.655 (2) and 3.676 (2) Å].

Details

Title: Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN 2)quinoline- κN]zinc
Authors: M H B Najib (Author) - Universiti Brunei Darussalam, Brunei
A L Tan (Author) - Universiti Brunei Darussalam, Brunei
David James Young (Author) - Universiti Brunei Darussalam, Brunei
S W Ng (Author) - University of Malaya, Malaysia
E R T Tiekink (Author) - University of Malaya, Malaysia
Publication details: Acta Crystallographica Section E: Structure Reports Online, Vol.68(Part 5), pp.m571-m572
Publisher: Wiley-Blackwell Publishing Inc.
Date published: 2012
DOI: 10.1107/S1600536812014390
ISSN: 1600-5368
Copyright note: Copyright © 2012 The Authors. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See: http://creativecommons.org/licenses/by/2.0/uk/legalcode
Organisation Unit: University of the Sunshine Coast, Queensland
Language: English
Record Identifier: 99449474902621
Output Type: Journal article

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Web Of Science research areas: Crystallography

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