Stainless steel 316 was examined for compatibility with the eutectic mixtures of NaCl + Na2CO3 and NaCl + Na2SO4 at 700 degrees C and Li2CO3 + K2CO3 + Na2CO3 at 450 degrees C in air for thermal energy storage. Electrochemical measurements combined with advanced microscopy and microanalysis techniques were employed. NaCl + Na2CO3 was found as the most aggressive salt at 700 degrees C. The attack morphology on the surface was uniform corrosion with no localized degradation at 450 degrees C. Microscopy observations showed grain boundary oxidative attack as the primary corrosion mechanism at 700 degrees C with depletion of alloying elements from grain boundaries.
Details
Title
Corrosion of stainless steel 316 in eutectic molten salts for thermal energy storage
Authors
Madjid Sarvghad (Corresponding Author) - Queensland University of Technology
Theodore A. Steinberg (Author) - Queensland University of Technology
Geoffrey Will (Author) - Queensland University of Technology
Publication details
Solar Energy, Vol.172, pp.198-203
Publisher
Elsevier Ltd
Date published
2018
DOI
10.1016/j.solener.2018.03.053
ISSN
1471-1257; 0038-092X
Grant note
Science and Engineering Faculty, QUT
Australian Solar Thermal Research Initiative (ASTRI) - Australian Government via the Australian Renewable Energy Agency (ARENA)