Brucinium toluene-4-sulfonate trihydrate at 130 K

G Smith; U D Wermuth; P C Healy; David James Young; J M White

doi:10.1107/S1600536805022695

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Brucinium toluene-4-sulfonate trihydrate at 130 K

Journal article

Open access

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Brucinium toluene-4-sulfonate trihydrate at 130 K

G Smith, U D Wermuth, P C Healy, David James Young and J M White

Acta Crystallographica Section E: Structure Reports Online, Vol.61(Part 8), pp.o2646-o2648

2005

DOI: https://doi.org/10.1107/S1600536805022695

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Abstract

The low-temperature (130 K) structure of the 1:1 proton-transfer compound of brucine with toluene-4-sulfonic acid (systematic name: 2,3-dimethoxy-10- oxostrychnidinium toluene-4-sulfonate trihydrate), C23H 27N2O4 +.C7H 7O3S-3H2O, has been determined. The asymmetric unit contains two cations, two anions and six molecules of water. Brucinium cations form the familiar undulating head-to-tail ribbon structures, which associate with the toluene-4-sulfonate anions and the water molecules in the interstitial cavities through hydrogen-bonding associations involving all available donor and acceptor atoms on all species. The result is a framework polymer structure. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved..

Details

Title: Brucinium toluene-4-sulfonate trihydrate at 130 K
Authors: G Smith (Author) - Queensland University of Technology
U D Wermuth (Author) - Griffith University
P C Healy (Author) - Griffith University
David James Young (Author) - Griffith University
J M White (Author) - University of Melbourne
Publication details: Acta Crystallographica Section E: Structure Reports Online, Vol.61(Part 8), pp.o2646-o2648
Publisher: Wiley-Blackwell Publishing Inc.
Date published: 2005
DOI: 10.1107/S1600536805022695
ISSN: 1600-5368
Copyright note: Copyright © 2005 The Authors. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See: http://creativecommons.org/licenses/by/2.0/uk/legalcode
Organisation Unit: University of the Sunshine Coast, Queensland
Language: English
Record Identifier: 99449583002621
Output Type: Journal article

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