Bis(4-carbamoylpiperidinium) biphenyl-4,4′-disulfonate

G Smith; U D Wermuth; David James Young

doi:10.1107/S1600536810045526

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Bis(4-carbamoylpiperidinium) biphenyl-4,4′-disulfonate

Journal article

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Bis(4-carbamoylpiperidinium) biphenyl-4,4′-disulfonate

G Smith, U D Wermuth and David James Young

Acta Crystallographica Section E: Structure Reports Online, Vol.66(Part 12), pp.o3160-o3161

2010

DOI: https://doi.org/10.1107/S1600536810045526

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Abstract

In the title isonipecotamide salt 2C6H 13N2O+·C12H8O 6S22-, the asymmetric unit comprises one biphenyl-4,4′-disulfonate dianion which lies across a crystallographic inversion centre and another in a general position [dihedral angle between the two phenyl rings is 37.1 (1)°], together with three isonipecotamide cations. Two of these cations give a cyclic homomeric amide-amide dimer inter-action [graph set R22(8)], the other giving a similar dimeric inter-action but across an inversion centre, both dimers then forming lateral cyclic R42(8) pyrimidinium-amide N - H⋯O inter-actions. These units are linked both laterally and longitudinally to the sulfonate groups of the dianions through piperidinium N - H⋯O hydrogen bonds, giving a three-dimensional framework structure.

Details

Title: Bis(4-carbamoylpiperidinium) biphenyl-4,4′-disulfonate
Authors: G Smith (Author) - Queensland University of Technology
U D Wermuth (Author) - Griffith University
David James Young (Author) - Griffith University
Publication details: Acta Crystallographica Section E: Structure Reports Online, Vol.66(Part 12), pp.o3160-o3161
Publisher: Wiley-Blackwell Publishing Inc.
Date published: 2010
DOI: 10.1107/S1600536810045526
ISSN: 1600-5368
Copyright note: Copyright © 2010 The Authors. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See: http://creativecommons.org/licenses/by/2.0/uk/legalcode
Organisation Unit: University of the Sunshine Coast, Queensland
Language: English
Record Identifier: 99449298002621
Output Type: Journal article

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