Journal article
Aurophilicity in tetraphenylphosphonium 7,8-bis(diphenylphosphino)-7,8- dicarba-nido-undecaborato-dibromo-digold(I)[PPh4][{(PPh 2)2-C2B9H10}(AuBr) 2]
Zeitschrift fur Anorganische und Allgemeine Chemie, Vol.633(15), pp.2689-2691
2007
Abstract
Reactions of tetraphenylphosphonium dibromoaurate(I) with 1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane in 2:1 ratio in acetone solution yields brown crystals shown to be the title compound. A single crystal X-ray study shows coordination of AuBr moieties by the phosphorus atoms of the ligand (Au-P 2.253(1), 2.246(1); Ag-Br 2.4041(7), 2.4067(7) Å), permitting a close Au⋯Au contact (2.9536(3)Å) with concomitant bending of the P-Au-Br arrays (173.99(4), 166.14(4)°) and a Br-Au⋯Au-Br torsion of 47.80(2)°.
Details
- Title
- Aurophilicity in tetraphenylphosphonium 7,8-bis(diphenylphosphino)-7,8- dicarba-nido-undecaborato-dibromo-digold(I)[PPh4][{(PPh 2)2-C2B9H10}(AuBr) 2]
- Authors
- Effendy (Author) - University of Western AustraliaP C Healy (Author) - Griffith UniversityC L Noack (Author) - Griffith UniversityB W Skelton (Author) - University of Western AustraliaA H White (Author) - University of Western AustraliaDavid James Young (Author) - Griffith University
- Publication details
- Zeitschrift fur Anorganische und Allgemeine Chemie, Vol.633(15), pp.2689-2691
- Publisher
- Wiley - V C H Verlag GmbH & Co. KGaA
- Date published
- 2007
- DOI
- 10.1002/zaac.200700339
- ISSN
- 0044-2313
- Organisation Unit
- University of the Sunshine Coast, Queensland
- Language
- English
- Record Identifier
- 99449302202621
- Output Type
- Journal article
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