Journal article
Asymmetric Synthesis of Indole Homo-Michael Adducts via Dynamic Kinetic Friedel-Crafts Alkylation with Cyclopropanes
Organic Letters, Vol.15(10), pp.2558-2561
2013
PMID: 23654283
Abstract
An enantioconvergent Friedel-Crafts alkylation of indoles with donor-acceptor cyclopropanes is described. The reaction is catalyzed by pybox center dot Mgl(2) and proceeds via a type I dynamic kinetic asymmetric transformation (DyKAT).
Details
- Title
- Asymmetric Synthesis of Indole Homo-Michael Adducts via Dynamic Kinetic Friedel-Crafts Alkylation with Cyclopropanes
- Authors
- Steven M. Wales (Author) - University of North Carolina at Chapel HillMorgan M. Walker (Author) - University of North Carolina at Chapel HillJeffrey S. Johnson (Corresponding Author) - University of North Carolina at Chapel Hill
- Publication details
- Organic Letters, Vol.15(10), pp.2558-2561
- Publisher
- American Chemical Society
- DOI
- 10.1021/ol4010646
- ISSN
- 1523-7052
- PMID
- 23654283
- Organisation Unit
- Student Services and Engagement; School of Science, Technology and Engineering
- Language
- English
- Record Identifier
- 99707484602621
- Output Type
- Journal article
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- Web Of Science research areas
- Chemistry, Organic
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