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Anion-Exchange Nanospheres as Titration Reagents for Anionic Analytes
Journal article   Peer reviewed

Anion-Exchange Nanospheres as Titration Reagents for Anionic Analytes

Jingying Zhai, Xiaojiang Xie and Eric Bakker
Analytical Chemistry, Vol.87(16), pp.8347-8352
2015
url
https://doi.org/10.1021/acs.analchem.5b01530View
Published Version

Abstract

Analytical Chemistry Chemical Engineering Other Chemical Sciences ion exchange ions nanospheres negative ions analytes anion exchange counterions sample solution titration reagents
We present here anion-exchange nanospheres as novel titration reagents for anions. The nanospheres contain a lipophilic cation for which the counterion is initially Cl-. Ion exchange takes place between Cl- in the nanospheres and a more lipophilic anion in the sample, such as ClO4 - and NO3 -. Consecutive titration in the same sample solution for ClO4 - and NO3 - were demonstrated. As an application, the concentration of NO3 - in spinach was successfully determined using this method.

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Chemistry, Analytical
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