(Acetato-κO)(acetato-κ2O,O′)[2-(3, 5-dimethyl-1H-pyrazol-1-yl-κN2)quinoline-κN]zinc(II)

M H B Najib; A L Tan; David James Young; S W Ng; E R T Tiekink

doi:10.1107/S1600536812025664

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(Acetato-κO)(acetato-κ2O,O′)[2-(3, 5-dimethyl-1H-pyrazol-1-yl-κN2)quinoline-κN]zinc(II)

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(Acetato-κO)(acetato-κ2O,O′)[2-(3, 5-dimethyl-1H-pyrazol-1-yl-κN2)quinoline-κN]zinc(II)

M H B Najib, A L Tan, David James Young, S W Ng and E R T Tiekink

Acta Crystallographica Section E: Structure Reports Online, Vol.68(Part 7), pp.m897-m898

2012

DOI: https://doi.org/10.1107/S1600536812025664

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Abstract

The ZnII atom in the title compound, [Zn(C2H 3O2)2(C14H13N 3)], is coordinated by an N2O3 donor set defined by the quinolinyl- and pyrazolyl-N atoms of the chelating heterocyclic ligand, and three carboxylate-O atoms derived from the monodentate and bidentate carboxylate ligands. Distortions from the ideal square-pyramidal coordination geometry relate to the restricted bite angle of the chelating ligands, i.e. O - Zn - O = 59.65 (5) and N - Zn - N = 76.50 (6)°, and the close approach of the non-coordinating carbonyl atom [Znâ‹¯O = 2.858 (2) Ã…]. In the crystal, molecules are consolidated into a three-dimensional architecture by C - Hâ‹¯O interactions © 2012 International Union of Crystallography.

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Title: (Acetato-κO)(acetato-κ2O,O′)[2-(3, 5-dimethyl-1H-pyrazol-1-yl-κN2)quinoline-κN]zinc(II)
Authors: M H B Najib (Author) - Universiti Brunei Darussalam, Brunei
A L Tan (Author) - Universiti Brunei Darussalam, Brunei
David James Young (Author) - Universiti Brunei Darussalam, Brunei
S W Ng (Author) - University of Malaya, Malaysia
E R T Tiekink (Author) - University of Malaya, Malaysia
Publication details: Acta Crystallographica Section E: Structure Reports Online, Vol.68(Part 7), pp.m897-m898
Publisher: Wiley-Blackwell Publishing Inc.
Date published: 2012
DOI: 10.1107/S1600536812025664
ISSN: 1600-5368
Copyright note: Copyright © 2012 The Authors. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See: http://creativecommons.org/licenses/by/2.0/uk/legalcode
Organisation Unit: University of the Sunshine Coast, Queensland
Language: English
Record Identifier: 99449373902621
Output Type: Journal article

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