Journal article
A volumetric study of molecular inclusion by α-cyclodextrin
Tetrahedron Letters, Vol.40(20), pp.3953-3956
1999
Abstract
The reaction volume (Δ vÌ„ c→0) associated with inclusion of 3- nitrophenol by αcyclodextrin was determined by densitometry to be -9 cm3 mol-1 while the corresponding value for encapsulation of methyl orange by two molecules of α-cyclodextrin is +27 cm3 mol-1. These volume changes can be interpreted in terms of displacement of solvent from the cavity of α- cyclodextrin and/or changes in solvation of the 'guest' molecule.
Details
- Title
- A volumetric study of molecular inclusion by α-cyclodextrin
- Authors
- N S Isaacs (Author) - University of Reading, United KingdomDavid James Young (Author) - Griffith University
- Publication details
- Tetrahedron Letters, Vol.40(20), pp.3953-3956
- Publisher
- Pergamon
- Date published
- 1999
- DOI
- 10.1016/S0040-4039(99)00619-X
- ISSN
- 0040-4039
- Organisation Unit
- University of the Sunshine Coast, Queensland
- Language
- English
- Record Identifier
- 99449323202621
- Output Type
- Journal article
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- Web Of Science research areas
- Chemistry, Organic
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Source: InCites