A new strategy for the stereoselective synthesis of 2,2 '-bipyrrolidines

Mary J. Gresser; Paul A. Keller; Steven M. Wales

doi:10.1016/j.tetlet.2009.06.068

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A new strategy for the stereoselective synthesis of 2,2 '-bipyrrolidines

Journal article

Peer reviewed

A new strategy for the stereoselective synthesis of 2,2 '-bipyrrolidines

Mary J. Gresser, Paul A. Keller and Steven M. Wales

Tetrahedron Letters, Vol.50(34), pp.4899-4902

2009

DOI: https://doi.org/10.1016/j.tetlet.2009.06.068

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Abstract

chiral bisamine

2,2'-bipyrrolidine

metathesis

asymmetric dihydroxylation

A new strategy for the stereoselective synthesis of the 2,2'-bipyrrolidine scaffold is presented using a metathesis reaction followed by asymmetric dihydroxylation for the introduction of the stereogenic elements. This straightforward high-yielding process is suitable for application to the synthesis of additional heterocycles. (C) 2009 Elsevier Ltd. All rights reserved.

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Title: A new strategy for the stereoselective synthesis of 2,2 '-bipyrrolidines
Authors: Mary J. Gresser (Author) - University of Wollongong
Paul A. Keller (Corresponding Author) - University of Wollongong
Steven M. Wales (Author) - University of Wollongong
Publication details: Tetrahedron Letters, Vol.50(34), pp.4899-4902
Publisher: Elsevier Ltd.
DOI: 10.1016/j.tetlet.2009.06.068
ISSN: 1873-3581
Organisation Unit: Student Services and Engagement; School of Science, Technology and Engineering
Language: English
Record Identifier: 99707484202621
Output Type: Journal article

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