Journal article
A Cyclic Porphyrin Tetramer Linked by Azo and Butadiyne Bridges
European Journal of Organic Chemistry, Vol.2010(23), pp.4381-4392
2010
Abstract
A soluble cyclic porphyrin oligomer (CPO) consisting of four 5,10‐diarylporphyrins linked by alternating azo and butadiyne bridges has been synthesised via an aminated dinickel(II) butadiyne dimer. This is the first cyclic tetramer that combines both azo and butadiyne bridges and extends the azoporphyrin family, which comprises only a very few examples. The electronic absorption spectrum of the tetramer is more similar to spectra of azoporphyrins than to those of butadiyne‐linked dimers or tetramer, exhibiting a two‐component Soret band with a splitting of 4190 cm–1 and a strongly red‐shifted Q band maximum at 735 nm.
Details
- Title
- A Cyclic Porphyrin Tetramer Linked by Azo and Butadiyne Bridges
- Authors
- Bruno Bašić (Author) - Queensland University of TechnologyJohn C McMurtrie (Author) - Queensland University of TechnologyDennis P Arnold (Author) - Queensland University of Technology
- Publication details
- European Journal of Organic Chemistry, Vol.2010(23), pp.4381-4392
- Publisher
- Wiley-VCH Verlag GmbH & Co. KGaA
- Date published
- 2010
- DOI
- 10.1002/ejoc.201000388
- ISSN
- 1099-0690; 1434-193X
- Copyright note
- This is the peer reviewed version of the following article: Bašić, B., McMurtrie, J.C. and Arnold, D.P. (2010), A Cyclic Porphyrin Tetramer Linked by Azo and Butadiyne Bridges. Eur. J. Org. Chem., 2010: 4381-4392. https://doi.org/10.1002/ejoc.201000388, which has been published in final form at https://doi.org/10.1002/ejoc.201000388. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.
- Organisation Unit
- School of Tertiary Access - Legacy; School of Education and Tertiary Access; University of the Sunshine Coast, Queensland
- Language
- English
- Record Identifier
- 99514907902621
- Output Type
- Journal article
Metrics
160 File views/ downloads
54 Record Views
InCites Highlights
These are selected metrics from InCites Benchmarking & Analytics tool, related to this output
- Web Of Science research areas
- Chemistry, Organic
UN Sustainable Development Goals (SDGs)
This output has contributed to the advancement of the following goals:
Source: InCites