Journal article
A Combined Voltammetric and Synchrotron Radiation-Grazing Incidence X-ray Diffraction Study of the Electrocrystallization of Zinc Tetracyanoquinodimethane
Australian Journal of Chemistry, Vol.65(3), pp.236-240
2012
Abstract
The in situ electrocrystallization of zinc tetracyanoquinodimethane (TCNQ) has been explored using synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD) at potentials in the region of the cyclic voltammetric peak where reduction of TCNQ to TCNQ– occurs at a Pt electrode in acetonitrile (0.1 M [NBu4][PF6]) solution containing Zn(NO3)2·6H2O. The in situ SR-GIXRD data along with ex situ IR and Raman spectroscopy results all confirmed the formation of the kinetically favoured phase of Zn[TCNQ]2(H2O)2 as the product.
Details
- Title
- A Combined Voltammetric and Synchrotron Radiation-Grazing Incidence X-ray Diffraction Study of the Electrocrystallization of Zinc Tetracyanoquinodimethane
- Authors
- J P Veder (Author) - Curtin University of TechnologyA Nafady (Author) - Monash UniversityG Clarke (Author) - Curtin University of TechnologyRoland De Marco (Author) - Curtin University of TechnologyA M Bond (Author) - Monash University
- Publication details
- Australian Journal of Chemistry, Vol.65(3), pp.236-240
- Publisher
- C S I R O Publishing
- DOI
- 10.1071/CH11361
- ISSN
- 0004-9425
- Organisation Unit
- University of the Sunshine Coast, Queensland; Office of the Deputy Vice-Chancellor (Research and Innovation)
- Language
- English
- Record Identifier
- 99449646802621
- Output Type
- Journal article
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- Chemistry, Multidisciplinary
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