1,3-oxygen to oxygen rearrangements of group IV esters

David James Young; Michael J T Robinson

doi:10.1016/S0040-4039(00)95554-0

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1,3-oxygen to oxygen rearrangements of group IV esters

Journal article

Peer reviewed

1,3-oxygen to oxygen rearrangements of group IV esters

David James Young and Michael J T Robinson

Tetrahedron Letters, Vol.28(31), pp.3631-3632

1987

DOI: https://doi.org/10.1016/S0040-4039(00)95554-0

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Abstract

Organic Chemistry

Medicinal and Biomolecular Chemistry

benzoic acid

The 1,3-oxygen to oxygen rearrangements of group IV esters of benzoic acid have been studied using 18O isotopic substitution: the free energies of activation for the intramolecular reactions fall from ~190 kJ mol-1 for 1A, to 76 for 1B, 59 for 1E, and <52 kJ mol-1 for 1F.

Details

Title: 1,3-oxygen to oxygen rearrangements of group IV esters
Authors: David James Young (Author) - University of Oxford, United Kingdom
Michael J T Robinson (Author) - University of Oxford, United Kingdom
Publication details: Tetrahedron Letters, Vol.28(31), pp.3631-3632
Publisher: Pergamon
Date published: 1987
DOI: 10.1016/S0040-4039(00)95554-0
ISSN: 0040-4039
Organisation Unit: University of the Sunshine Coast, Queensland
Language: English
Record Identifier: 99449354502621
Output Type: Journal article

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