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1,2-Distannylation and -disilylation of cyclic allenes
Journal article   Peer reviewed

1,2-Distannylation and -disilylation of cyclic allenes

K Kwetkat, B H Riches, J M Rosset, D J Brecknell, K Byriel, C H L Kennard, David James Young, U Schneider, T N Mitchell and W Kitching
Chemical Communications, Vol.6, pp.773-774
1996
url
https://doi.org/10.1039/CC9960000773View
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Abstract

cyclic allenes
Cyclo-1,2-dienes (C9-C13) are converted into the synthetically promising 2,3-bis(trimethylsilyl)- and 2,3-bis-(trimethylstannyl)cycloalk-1-enes by disilylation with lithium chlorotrimethylsilane in tetrahydrofuran, and Pd0-catalysed addition of hexaalkyldistannes, respectively.

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