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Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals
Journal article   Open access   Peer reviewed

Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals

Shi-Qiang Bai, David James Young and T S Andy Hor
Molecules, Vol.22(10), 1600
2017
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Published VersionPDF - Published Version (Open Access)CC BY V4.0 Open Access
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https://doi.org/10.3390/molecules22101600View
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Abstract

structural relationship H-bonding crystal growth 1,2,3-triazole luminescence
Quinoline-triazoles 2-((4-(diethoxymethyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (1), 2-((4-(m-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (2) and 2-((4-(p-tolyl)-1H-1,2,3-triazol-1- yl)methyl)quinoline (3) have been prepared with CuAAC click reactions and used as a model series to probe the relationship between lattice H-bonding interaction and crystal direction of growth. Crystals of 1-3 are 1D tape and prism shapes that correlate with their intermolecular and solvent 1D lattice H-bonding interactions. All compounds were thermally stable up to about 200 â—¦C and blue-green emissive in solution.

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